Journal of the American Chemical Society p. 8209 - 8217 (1984)
Update date:2022-08-05
Topics:
Hart, David J.
Tsai, Yeun-Min
α-Acylamino radicals 1-3 can be generated by tri-n-butyltin radical mediated cleavage of a carbon-sulfur bond.These radicals cyclize with good regio- and stereoselectivity to afford pyrrolizidinones.Cyclization products 12a and 23a were converted to the alkaloid isoretronecanol (4).
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