Cyclopropanation of enantiopure metal alkenyl carbenes with 2-methoxyfuran: A practical route to carboxycyclopropylglycine precursors

DOI: 10.1002/chem.200601332

Source and publish data:

Chemistry - A European Journal p. 1326 - 1331 (2007)

Update date:2022-08-05

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Authors:

Barluenga, Jose

De Prado, Ana

Santamaria, Javier

Tomas, Miguel

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Article abstract of DOI:10.1002/chem.200601332

We have examined the reactivity of enantiopure alkenyl Fischer carbene complexes 1, readily available from the chiral pool, with 2-methoxyfuran 4. In this reaction, polyfunctionalised cyclopropylcarbenes 5 are obtained under very mild conditions and with

Full text of DOI:10.1002/chem.200601332

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