A Stable Intermediate in the Sommelet-Hauser Rearrangement of 1-Methyl-2-phenyl-piperidinium 1-Methylides: The Improved Sommelet-Hauser Rearrangement

DOI: 10.1039/c39880000370

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 370 (1988)

Update date:2022-08-05

Topics:

Authors:

Shirai, Naohiro

Sumiya, Fumihiko

Sato, Yoshiro

Hori, Mikiko

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Article abstract of DOI:10.1039/c39880000370

Reaction of 1-methyl-1-(trimethylsilyl)methyl-2-(substituted phenyl)piperidinium iodides (2) with caesium fluoride gave high yields of 2-methyl-1,3,4,5,6,11a-hexahydro-2H-2-benzazonines (4) which are regarded as unstable intermediates in the Sommelet-Haus

Full text of DOI:10.1039/c39880000370

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