A facile one-step synthesis of ethyl 2-(1,1-dialkyl and arylmethyl) malonates

Article abstract of DOI:10.1080/00397919908085773

Diethyl ethoxymethylenemalonate (EMME) is unexpectedly converted into diethyl 2-(1,1-dialkyl and diarylmethyl) malonate derivatives by a classical Grignard reaction. Addition of organocuprates to EMME gave diethyl 2-(1- ethoxyalkyl) malonate derivatives.

Full text of DOI:10.1080/00397919908085773

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A Facile One-Step Synthesis
of Ethyl 2-(L,L-Dialkyl and
Arylmethyl) Malonates
Young Mee Kim a , Tae Woo Kwon a , Sung Kee Chung
b & Michael B. Smith c
a Department of Chemistry , Kyung Sung University ,
Pusan, 608-736, Korea
b Department of Chemistry , Pohang University of
Science and Technology , Pohang, 790-600, Korea
c Department of Chemistry , University of
Connecticut , Room 151, 215 Glenbrook Road,
Storrs, Connecticut, 06269-3060
Published online: 17 Sep 2007.
To cite this article: Young Mee Kim , Tae Woo Kwon , Sung Kee Chung &
Michael B. Smith (1999) A Facile One-Step Synthesis of Ethyl 2-(L,L-Dialkyl and
Arylmethyl) Malonates, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 29:2, 343-350, DOI:
10.1080/00397919908085773
To link to this article: http://dx.doi.org/10.1080/00397919908085773
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