Tetrahedron Letters p. 3437 - 3440 (1984)
Update date:2022-08-04
Topics:
Brennenstuhl, Werner
Hanack, Michael
1-Bromo-1-cyclopropyl-2-methyl-1-propene (7) does not react with cyclohexene and AgSbF6 with formation of the expected cycloadduct 9.The first generated cyclopropylvinyl-cation 8 rearranges to the allyl-cation 10 which after addition to the olefins cyclohexene and 2,3-dimethyl-2-butene (19) via unusual rearrangements gives the dienes 17 and 20 respectively.
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