Tetrahedron Letters p. 3437 - 3440 (1984)
Update date:2022-08-04
Topics:
Brennenstuhl, Werner
Hanack, Michael
1-Bromo-1-cyclopropyl-2-methyl-1-propene (7) does not react with cyclohexene and AgSbF6 with formation of the expected cycloadduct 9.The first generated cyclopropylvinyl-cation 8 rearranges to the allyl-cation 10 which after addition to the olefins cyclohexene and 2,3-dimethyl-2-butene (19) via unusual rearrangements gives the dienes 17 and 20 respectively.
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Doi:10.1021/jo00200a046
(1984)Doi:10.1016/S0040-4039(01)90195-9
(1984)Doi:10.1016/j.tetasy.2006.12.023
(2007)Doi:10.1021/jo01051a520
(1962)Doi:10.1002/anie.201603260
(2016)Doi:10.1021/jm060964m
(2007)
