Electronic Control of Stereoselectivity. 27. The Effect of Apical Spirocyclopropane Substitution on the Stereochemical Course of Diels-Alder Cycloadditions to Norbornyl-Fused Diene Systems

DOI: 10.1021/ja00338a037

Source and publish data:

Journal of the American Chemical Society p. 8232 - 8240 (1984)

Update date:2022-08-05

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Authors:

Paquette, Leo A.

Green, Kenneth E.

Gleiter, Rolf

Schaefer, Wolfgang

Gallucci, Judith C.

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Article abstract of DOI:10.1021/ja00338a037

The three new 7-spirocyclopropyl-substituted isodicyclopentadiene analogues 1-3 were prepared, and their stereoselective behavior toward various dienophiles was evaluated.Whereas the unadorned diene 1 exhibits no strong predilection for above-plane or bel

Full text of DOI:10.1021/ja00338a037

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