Tetrahedron p. 2297 - 2302 (1984)
Update date:2022-09-26
Topics:
Chamberlin, A. Richard
Mulholland, Robert L.
Reaction of electrophiles with a variety of acyclic allylic alcohols was investigated.Both aqueous iodine and acetylhypoiodite convert certain alkenols into iodo diols and acetoxy iodo alcohols, respectively, with regio- and stereoselectivities as high as 99percent.Protection of alcohol group lowers the selectivity only slightly.Structural factors that control the regioselectivity of iodohydrin formation in these substrates have been delineated.Some of the iodo diols have been deiodinated, illustrating a simple two step procedure for converting allylic alcohols into threo-1,3-diols.
View MoreZibo Linzi Darong Fine Chemical Co., Ltd(expird)
Contact:86-532-67773200; 15689126900
Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Dalian RSD International Trade Co.,Ltd.(expird)
Contact:86-22-60875058 58610575
Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Contact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
HENAN NEW BLUE CHEMICAL CO.,LTD
website:http://www.newbluechem.com
Contact:86-371-55170693/55170694
Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China
Hangzhou yi lu biont technology Co., LTD
Contact:+86-571-88152630
Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Doi:10.1021/jm1014549
(2011)Doi:10.1016/j.tetlet.2007.02.046
(2007)Doi:10.1016/j.ejphar.2007.12.006
(2008)Doi:10.1021/ja066485u
(2007)Doi:10.1021/jm00147a037
(1985)Doi:10.1016/S0040-4020(01)89958-0
(1987)
