Asymmetric synthesis of ring functionalized trans-2,6-disubstituted piperidines from N-sulfinyl δ-amino β-keto phosphonates. Total synthesis of (-)-myrtine

DOI: 10.1021/jo062365t

Source and publish data:

Journal of Organic Chemistry p. 2046 - 2052 (2007)

Update date:2022-09-26

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Authors:

Davis, Franklin A.

Xu, He Xu, He

Zhang, Junyi

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Article abstract of DOI:10.1021/jo062365t

Sulfinimine-derived N-sulfinyl δ-amino β-ketophosphonates are transformed via the enaminones to the phosphoryl dihydropyridones that selectively give trans-2,6-disubstituted 1,2,5,6-tetrahydropyridines on organocuprate addition and dephosphorylation.

Full text of DOI:10.1021/jo062365t

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