Solution and Flash Vacuum Pyrolyses of β-(3,5-Disubstituted-phenyl)ethanesulfonyl Azides. Sultam, Pyrindine, and Azepine Formation

DOI: 10.1021/jo00200a022

Source and publish data:

Journal of Organic Chemistry p. 5124 - 5131 (1984)

Update date:2022-08-03

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Authors:

Abramovitch, Rudolph A.

Holcomb, William D.

Thompson, W. Marshall

Wake, Shigeo

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Article abstract of DOI:10.1021/jo00200a022

The solution and flash vacuum pyrolyses of β-(3,5-disubstituted-phenyl)ethanesulfonyl azides are reported.When R = Me, FVP results suggest that the substituents stabilize the intermediate leading to the 3,4-dihydro-2,1-benzothiazepine 2,2-dioxide (6a).A n

Full text of DOI:10.1021/jo00200a022

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