Chinese Journal of Chemistry p. 15 - 17 (2013)
Update date:2022-07-30
Topics:
Deng, Gang
Huang, Zuogang
Zhao, Xiaolong
Li, Zheng
Li, Yuanchao
Jiang, Biao
A procedure for the stereospecific synthesis of drospirenone has been developed. The key steps included the stereospecific reduction of the C 7-tertiary alcohol with ZnI2/Et3SiH, a novel mild and stereospecific tertiary alcohol reduction system, and the tandem oxidation/cyclopropanation reactions. Copyright
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Doi:10.1021/jo0701029
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