Journal of Organic Chemistry p. 194 - 201 (1985)
Update date:2022-08-04
Topics:
Jacobson, Barry M.
Arvanitis, Georgia M.
Eliasen, Carol A.
Mitelman, Rimma
The rates of the ene reactions between diethyl diazenedicarboxylate and a number of dienes have been measured and product structures determined.Accelerated reactions are observed with 1,3-cyclohexadienes but not with dienes held fixed in the s-trans form.Within the first set of systems tertiary hydrogens are much more reactive than secondary.Within the second set secondary are (in turn) more reactive than primary.There is no apparent correlation between the rate of the Diels-Alder reaction of the 1,3-cyclohexadienes with maleic anhydride and the rate of ene reaction with the diazenedicarboxylate.
View MoreTianjin Jingye Fine Chemicals Co., Ltd.
Contact:+86-15722078107; +86-22-26911407
Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China
Anhui Xinyuan Technology Co.,Ltd
website:http://www.ahxytech.com/
Contact:0086-559-3515800
Address:Huangshan City of Anhui Province Huizhou Huizhou District Road, 21-9
website:http://www.simagchem.com
Contact:+86-592-2680277
Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Shanghai Gsyn Chemical Co.,Ltd.
Contact:86-021-67158290
Address:86-021-67158291
Contact:+86-512-56795332
Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
Doi:10.1016/j.ica.2007.02.048
(2007)Doi:10.1021/ja071622o
(2007)Doi:10.1002/ejoc.200700074
(2007)Doi:10.1016/j.tetlet.2007.04.010
(2007)Doi:10.1021/acsmedchemlett.9b00194
(2019)Doi:10.1021/jo101902z
(2010)
