The Synthesis of Mixed-valence Dirhodium Carbonyl Complexes, and the X-Ray Crystal Structures of 2> and 2> (R = p-Tolyl)

DOI: 10.1039/c39840001025

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1025 - 1027 (1984)

Update date:2022-09-26

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Authors:

Connelly, Neil G.

Finn, Crispin J.

Freeman, Mark J.

Orpen, A. Guy

Stirling, Janet

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Article abstract of DOI:10.1039/c39840001025

X-Ray structural studies on <2>^z+ (R = p-tolyl, z = 0 and 1) show that the mixed-valence cation is formed by electron-loss from a metal-metal anti-bonding orbital; the asymmetric compounds 2>^z+ result from the oxidatively induced substitution of 2>.

Full text of DOI:10.1039/c39840001025

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