Synthetic Communications p. 2019 - 2030 (2007)
Update date:2022-08-03
Topics:
Page, Philip C. Bulman
Allin, Steven M.
Dilly, Suzanne J.
Buckley, Benjamin R.
The synthesis of several novel polymer-supported aziridine-containing aminoalcohol chiral ligands has been accomplished, and the polymers have been used as ligands for the catalytic asymmetric addition of diethylzinc to benzaldehyde, giving up to 89% ee. Incorporation onto a polymer support prevents the variation of ee with time that is observed in reactions of one unsupported ligand, perhaps as a result of site isolation of the ligand within the polymer, preventing cooperative effects. Copyright Taylor & Francis Group, LLC.
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(2007)
