SILAFUNCTIONAL COMPOUNDS IN ORGANIC SYNTHESIS. 28. CONJUGATE ADDITION OF A HYDROXYMETHYL ANION SYNTHON TO α,β-ENONES

DOI: 10.1016/S0040-4039(01)81408-8

Source and publish data:

Tetrahedron Letters p. 4249 - 4252 (1984)

Update date:2022-07-30

Topics:

Authors:

Tamao, Kohei

Ishida, Neyoshi

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Article abstract of DOI:10.1016/S0040-4039(01)81408-8

The title reaction has been achieved by a sequence of the copper-catalyzed conjugate addition of the (allyldimethylsilyl)methyl Grignard reagent, fluorodeallylation and the H2O2-oxidation of the carbon-silicon bond therein.

Full text of DOI:10.1016/S0040-4039(01)81408-8

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Product name:Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-

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