SILAFUNCTIONAL COMPOUNDS IN ORGANIC SYNTHESIS. 28. CONJUGATE ADDITION OF A HYDROXYMETHYL ANION SYNTHON TO α,β-ENONES

DOI: 10.1016/S0040-4039(01)81408-8

Source and publish data:

Tetrahedron Letters p. 4249 - 4252 (1984)

Update date:2022-07-30

Topics:

Authors:

Tamao, Kohei

Ishida, Neyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)81408-8

The title reaction has been achieved by a sequence of the copper-catalyzed conjugate addition of the (allyldimethylsilyl)methyl Grignard reagent, fluorodeallylation and the H2O2-oxidation of the carbon-silicon bond therein.

Full text of DOI:10.1016/S0040-4039(01)81408-8

Products guided by the article

Product name:Cyclohexanone, 3-[(dimethyl-2-propenylsilyl)methyl]-3,5,5-trimethyl-

Cas No:94616-88-3

R&D Labs maybe for 94616-88-3

Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】

website:http://www.chemboss.com.cn

Contact:+86-531-58591595

Address:No2.Hualong Road, Jinan, China
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
JIEJIE GROUP CO.,LTD.

Contact:+86 021-51698675

Address:1701, Jielong Plaza, No.618 Pingliang Rd, ShangHai,China

Relevant to this article

Synthesis and biological activity of azido analogues of 5,6-dimethylxanthenone-4-acetic acid for use in photoaffinity labeling

Doi:10.1021/jm0702175
(2007)
A singlet aryl-CF₃ carbene: 2-benzothienyl(trifluoromethyl) carbene and interconversion with a strained cyclic allene

Doi:10.1021/ol071290s
(2007)
An efficient copper(I) iodide catalyzed synthesis of diaryl selenides through Cse bond formation using solvent acetonitrile as ligand

Doi:10.1055/s-0030-1260078
(2011)
Synthesis of New Pyrrolo[2, 3-b]pyridines as a Potent Inhibitor of Tumour Necrosis Factor Alpha

Doi:10.1002/ardp.200300773
(2004)
3-(Arylamino)-1,2,4-triazin-5-one: A novel synthesis and its use

Doi:10.1002/ejoc.201000242
(2010)
Structural Effects on the Intramolecular Electron Transfer Induced Decomposition of a Series of 1,2-Dioxetanes Derived from 9-Alkylidene-10-methylacridans

Doi:10.1021/ja00531a026
(1980)

Article Doi