Reactions of vanadocene with benzyl bromide

DOI: 10.1016/0022-328X(88)80155-4

Source and publish data:

Journal of Organometallic Chemistry p. 313 - 324 (1988)

Update date:2022-08-04

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Authors:

Sustmann, Reiner

Kopp, Gebhard

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Article abstract of DOI:10.1016/0022-328X(88)80155-4

The formation of bibenzyl in the reaction of vanadocene with benzyl bromide is explained in terms of an initial oxidative addition of benzyl bromide and subsequent free radical reactions.ESR evidence is presented for the V^IV intermediate.

Full text of DOI:10.1016/0022-328X(88)80155-4

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