UNUSUAL STERIC EFFECT OF AN ALKENYL OR ARYL GROUP ON THE DISSOCIATIVE REDUCTIVE ELIMINATION FROM cis-ALKENYL(OR -ARYL)DIMETHYL(TRIPHENYLPHOSPHINE)GOLD(III)

DOI: 10.1016/0022-328X(87)83038-3

Source and publish data:

Journal of Organometallic Chemistry p. C31 - C34 (1987)

Update date:2022-08-04

Topics:

Authors:

Komiya, Sanshiro

Shibue, Akira

Ozaki, Satoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)83038-3

A sterically bulky aryl or alkenyl group directly bonded to gold suppresses the rate of dissociation of the triphenylphosphine ligand from cis-alkenyl(or -aryl)dimethyl(triphenylphosphine)gold(III) leading to selective reductive elimination.

Full text of DOI:10.1016/0022-328X(87)83038-3

Products guided by the article

Product name:cis-dimethyl(o-tolyl)(triphenylphosphine)gold(III)

Cas No:94889-67-5

R&D Labs maybe for 94889-67-5

Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province
Hubei Onward Bio-Development Co., Ltd.

Contact:+86-718-8417012

Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Win-Win chemical Co.Ltd

website:http://www.win-winchemical.com

Contact:0086-577-64498589

Address:6F, No. 396 Xingping Road, Longwan Industrial Zone, Wenzhou City, Zhejiang, 325000 P.R.China

Relevant to this article

Utilization of the versatility of sulfur in C-C bond formation and cleavage: Synthesis of ABC taxoid skeletons

Doi:10.1002/ejoc.200700301
(2007)
Posttreatment technique for S_N2 alkylation of aromatics with alkyl halides: Aiming toward large-scale synthesis of building blocks for soft π-molecular materials

Doi:10.1246/bcsj.20180075
(2018)
Synthesis and SARs of dopamine derivatives as potential inhibitors of influenza virus PA_N endonuclease

Doi:10.1016/j.ejmech.2020.112048
(2020)
Synthesis and Surface Behaviour of NDI Chromophores Mounted on a Tripodal Scaffold: Towards Self-Decoupled Chromophores for Single-Molecule Electroluminescence

Doi:10.1002/chem.202101264
(2021)
A NEW AND CONVENIENT SYNTHESIS OF ARYL-SUBSTITUTED BUTATRIENES USING NICKEL-CATALYZED COUPLING OF ARYL-SUBSTITUTED 1,1-DIBROMOETHENES

Doi:10.1246/cl.1984.2005
(1984)
Synthesis of thiophenoacetyl-1,4-benzoquinones

Doi:10.1515/HC.2006.12.6.463
(2006)

Article Doi