UNUSUAL STERIC EFFECT OF AN ALKENYL OR ARYL GROUP ON THE DISSOCIATIVE REDUCTIVE ELIMINATION FROM cis-ALKENYL(OR -ARYL)DIMETHYL(TRIPHENYLPHOSPHINE)GOLD(III)

DOI: 10.1016/0022-328X(87)83038-3

Source and publish data:

Journal of Organometallic Chemistry p. C31 - C34 (1987)

Update date:2022-08-04

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Authors:

Komiya, Sanshiro

Shibue, Akira

Ozaki, Satoshi

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Article abstract of DOI:10.1016/0022-328X(87)83038-3

A sterically bulky aryl or alkenyl group directly bonded to gold suppresses the rate of dissociation of the triphenylphosphine ligand from cis-alkenyl(or -aryl)dimethyl(triphenylphosphine)gold(III) leading to selective reductive elimination.

Full text of DOI:10.1016/0022-328X(87)83038-3

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