Tetrahedron Letters p. 69 - 72 (1984)
Update date:2022-08-04
Topics:
Oae, Shigeru
Kawai, Tsutomu
Furukawa, Naomichi
The reaction of benzyl or 1-phenylethyl 2-pyridyl sulfoxide with Grignard reagent proceeds via a ?-sulfurane as an intermediate to give the coupling product, 2-benzylpyridine or 2-(1-phenylethyl)pyridine in quantitative yield.Stereochemistry for this reaction is complete retention at the benzylic carbon atom.
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(1984)
