Perchlorovinylcarbene: a Bulky Electrophile

DOI: 10.1039/c39840001528

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1528 - 1529 (1984)

Update date:2022-09-26

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Authors:

Kostikov, Rafael

Meijere, Armin de

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Article abstract of DOI:10.1039/c39840001528

The carbene selectivity index m_CXY for perchlorovinylcarbene was determined by competition experiments with different substituted olefins as ca. 0.38, whereas the value calculated from Moss's equation is 0.34 +/- 0.1; this proves at least qualitatively that perchlorovinylcarbene is an electrophilic carbene.

Full text of DOI:10.1039/c39840001528

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