Helvetica Chimica Acta p. 487 - 492 (1992)
Update date:2022-07-29
Topics:
Nishio, Takehiko
A synthetically useful C-C bond formation involving the photochemical addition of quinoxaline-2(1H)-thiones to alkenes is described.Irradiation of the quinoxaline-2(1H)-thiones 1-4 in the presence of the alkenes 7 gave the 2-(2'-mercaptoalkyl)quinoxalines 8-11 in moderate-to-good yields via ring cleavage of an intermediate aminothietane with aromatization of the quinoxaline ring.The latter was formed by <2+2> photocycloaddition of the C=S bond of the quinoxaline-2(1H)-thione and the C=C bond of the alkene.
View MoreHangzhou Neway Chemicals Co., Ltd.
Contact:+86-571-85095566
Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
website:http://www.sigmaaldrich.com
Contact:800 558-9160
Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
Chemsky（shanghai）International Co.,Ltd.
Contact:0
Address:0
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED
Contact:86-419-2390789
Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
Anhui New Star Pharmaceutical Development Co., Ltd
Contact:013956922763
Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Doi:10.1016/j.tet.2007.07.068
(2007)Doi:10.1021/ic701414v
(2007)Doi:10.1016/j.tetasy.2010.04.064
(2010)Doi:10.1039/b614444f
(2007)Doi:10.1002/jhet.5570440536
(2007)Doi:10.1002/ardp.200800048
(2008)
