Generation and Trapping of a C-Unsubstituted Methylenephosphine Sulphide

DOI: 10.1039/c39840001214

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1214 - 1215 (1984)

Update date:2022-08-04

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Authors:

Deschamps, Eliane

Mathey, Francois

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Article abstract of DOI:10.1039/c39840001214

The synthesis of a 7-phosphabicyclo<2.2.2>octa-2,5-diene P-sulphide is described; on thermolysis in boiling toluene, this compound generates Ph-P(S)=CH2 which can be trapped by methanol, 2,3-dimethylbutadiene, and benzylideneacetophenone.

Full text of DOI:10.1039/c39840001214

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