Generation and Trapping of a C-Unsubstituted Methylenephosphine Sulphide

DOI: 10.1039/c39840001214

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1214 - 1215 (1984)

Update date:2022-08-04

Topics:

Authors:

Deschamps, Eliane

Mathey, Francois

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840001214

The synthesis of a 7-phosphabicyclo<2.2.2>octa-2,5-diene P-sulphide is described; on thermolysis in boiling toluene, this compound generates Ph-P(S)=CH2 which can be trapped by methanol, 2,3-dimethylbutadiene, and benzylideneacetophenone.

Full text of DOI:10.1039/c39840001214

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2-Phosphabicyclo[2.2.2]octa-5,7-diene-5,6-dicarboxylic acid, 4,8-dimethyl-1,2-diphenyl-, dimethyl ester, 2-sulfide

Cas No:95202-94-1

R&D Labs maybe for 95202-94-1

Wuhan Silworld Chemical Co.,Ltd

website:http://www.silworldchemical.com

Contact:+86-27-85613400

Address:No.198 jiangjun Road, Wuhan,China 430033
Chengdu Gelipu Biotechnology Co., Ltd.

website:http://www.glp-china.com

Contact:86-28-82610909

Address:chegndu
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Richest Group Ltd.

Contact:+86 21 5017 5386

Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China

Relevant to this article

Henry condensations with 4,6-O-benzylidenylated and non-protected D-glucose and L-fucose via DBU-catalysis

Doi:10.1016/S0040-4039(03)01328-5
(2003)
Synthesis and characterization of 2H-pyrano[3,2-c]coumarin derivatives and their photochromic and redox properties

Doi:10.1016/j.tet.2007.07.041
(2007)
Catalytic hydroarylation of olefins promoted by dicationic platinum(II) and palladium(II) complexes. the interplay of C-C bond formation and M-C bond cleavage

Doi:10.1021/om700692s
(2007)
Novel synthesis of naturally occurring pulvinones: A heck coupling, transesterification, and Dieckmann condensation strategy

Doi:10.1055/s-2007-983803
(2007)
Synthesis and anti-tumor activities of a novel series of tricyclic 1-anilino-5H-pyridazino[4,5-b]indoles

Doi:10.1002/ardp.200700078
(2007)
Synthesis of oxepane ring containing monocyclic, conformationally restricted bicyclic and spirocyclic nucleosides from D-glucose: A cycloaddition approach

Doi:10.1021/jo070846m
(2007)

Article Doi