Journal of the Chemical Society, Dalton Transactions p. 2695 - 2702 (1984)
Update date:2022-08-05
Topics:
Edwards, Peter
Wilkinson, Geoffrey
A number of trioxorhenium(VII) compounds of the type ReO3X (X = NPri2, OMe, OBut, or O2CR; R = Me, CF3, But, or Ph) have been prepared from ReO3Cl, ReO3(OSiMe3), and Re2O7.The copounds form adducts with tetrahydrofuran, pyridine (py), 2-hydroxypyridine, and NNN'N'-tetramethylethylenediamine (tmen); examples are ReO3(OMe)(tmen) and ReO3(O2CMe)(py).For the carboxylates, the RCO2 group may be unidentate or chelate depending upon the nature of the additional ligand.The acetatotrioxo-complex undergoes an exchange reaction with benzoic acid to give the corresponding benzoate.A five-co-ordinate rhenium(VII) complex with trimethylsilyl-amide, -imide, and -oxide groups, Re
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Doi:10.1016/0022-328X(84)80723-8
(1984)Doi:10.1021/acs.joc.8b02395
(2018)Doi:10.1021/jo00210a021
(1985)Doi:10.1021/jo00210a006
(1985)Doi:10.1007/s10593-007-0078-x
(2007)Doi:10.1016/j.jorganchem.2007.05.040
(2007)
