Journal of Organic Chemistry p. 3089 - 3098 (1988)
Update date:2022-08-04
Topics:
Oku, Akira
Harada, Toshiro
Hattori, Kazuhiro
Nozaki, Yohko
Yamaura, Yasunari
Primary alkoxides (R1CH2OM; M=K or Li) when treated with haloalkenes (R3R4C=CXY; X=Cl or Br, Y=H or Cl) in the presence of n-BuLi in THF at 0 deg C gave allylic alcohols (R1CH(OH)CH=CR3R4) through the insertion reaction of the corresponding alkylidenemethylene carbenoid (
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