Journal of Organic Chemistry p. 1916 - 1922 (1987)
Update date:2022-08-04
Topics:
Chauvet, F.
Heumann, A.
Waegell, B.
The oxidation of various norbornene derivatives and several mono- and nonconjugated diolefines with the catalyst (CH3CN)2PdCl(NO2) (1) is described.In contrast with the results previously observed with Wacker-type catalysts (PdCl2-CuCl2), the epoxidation process is selective for the strained norbornene double bond with dienes 5 or 7.Methyl ketones such as 14, 16, 18, and 20 are obtained with unhindered terminal olefins (e.g., 20 from 19).The solution structure of bis(μ-chloro)bis
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