Tetrahedron p. 6231 - 6244 (1992)
Update date:2022-08-02
Topics:
Corriu, Robert J. P.
Huynh, Vilam
Iqbal, Javed
Moreau, Joel J. E.
Vernhet, Claude
The reactions of lithium N,N-bis(trimethylsilyl)aminomethyl acetylide with electrophilic reagents offered a short preparation of substituted and functional propargyl amines.These are shown to be useful precursors of various saturated protected primary amines.Addition reactions to the carbon-carbon triple bond or isomerisation reactions gave rise to allylic, dienic and α-allenic amines. Keywords: Silylamines; propargylamines, α-allenylamines; N,N-bis(silyl)dienamines.
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