A RING OPENING REACTION OF OXETANES WITH LITHIUM ACETYLIDES PROMOTED BY BORON TRIFLUORIDE ETHERATE

DOI: 10.1016/S0040-4020(01)98801-5

Source and publish data:

Tetrahedron p. 4261 - 4266 (1984)

Update date:2022-07-29

Topics:

Authors:

Yamaguchi, Masahiko

Nobayashi, Yukio

Hirao, Ichiro

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Article abstract of DOI:10.1016/S0040-4020(01)98801-5

Several substituted oxetanes were treated with lithium acetylides in the presence of boron trifluoride etherate to give γ-hydroxyacetylenes.The reaction conditions were varied and several synthetic features of the present reaction were revealed.

Full text of DOI:10.1016/S0040-4020(01)98801-5

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