STEREOSPECIFIC PHENYLATION OF ALKENYLSILANES WITH PHENYLPALLADIUM ACETATE

DOI: 10.1016/S0040-4039(01)81687-7

Source and publish data:

Tetrahedron Letters p. 5789 - 5792 (1984)

Update date:2022-08-05

Topics:

Authors:

Kikukawa, Kiyoshi

Ikenaga, Kazutoshi

Wada, Fumio

Matsuda, Tsutomu

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Article abstract of DOI:10.1016/S0040-4039(01)81687-7

(E)- and (Z)-RCH=CHSiMe3 (R= Ph, n-C6H13, CH3OCH2) reacted stereospecifically with Ph-Pd-OAc to give RCH=C(Ph)SiMe3 and R(Ph)C=CHSiMe3 with inversion of the starting geometry with respect to R and Me3Si groups.

Full text of DOI:10.1016/S0040-4039(01)81687-7

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