Tetrahedron Letters p. 5789 - 5792 (1984)
Update date:2022-08-05
Topics:
Kikukawa, Kiyoshi
Ikenaga, Kazutoshi
Wada, Fumio
Matsuda, Tsutomu
(E)- and (Z)-RCH=CHSiMe3 (R= Ph, n-C6H13, CH3OCH2) reacted stereospecifically with Ph-Pd-OAc to give RCH=C(Ph)SiMe3 and R(Ph)C=CHSiMe3 with inversion of the starting geometry with respect to R and Me3Si groups.
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