Tetrahedron Letters p. 79 - 82 (1985)
Update date:2022-08-04
Topics:
Ishihara, Takashi
Yamasaki, Yasuhiro
Ando, Teiichi
Treatment of F-alkylacetylenes, generated in situ from 1H-F-1-alkenephosphonates, with silyl enol ethers in the presence of a catalytic amount of tetrabutylammonium fluoride gives good yields of F-alkyl-substituted propargyl alcohols or 4-(1H-F-alkylidene)-1,3-dioxolane derivatives, the latter being converted to the corresponding α-hydroxy ketones.
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