STOICHIOMETRIC GENERATION OF MAGNESIUM HOMOENOLATE EQUIVALENTS FROM ACYLTRIMETHYLSILANES. SYNTHESIS OF 1,6-DIKETONE DERIVATIVES

DOI: 10.1016/S0040-4039(01)81590-2

Source and publish data:

Tetrahedron Letters p. 5307 - 5310 (1984)

Update date:2022-07-30

Topics:

Authors:

Enda, Jun

Matsutani, Tomohiro

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(01)81590-2

Treatment of various acyltrimethylsilanes with vinylmagnesium bromide has allowed a stoichiometric generation of the corresponding 3-(trimethyl-siloxy)allylmagnesiums, which, in the presence copper(I) trimethylsilyl-acetylide, undergo conjugate addition t

Full text of DOI:10.1016/S0040-4039(01)81590-2

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