DIASTEREOSELECTIVE IRELAND-CLAISEN REARRANGEMENT OF ALLYLIC ALCOHOLS

DOI: 10.1016/S0040-4039(01)81579-3

Source and publish data:

Tetrahedron Letters p. 5263 - 5266 (1984)

Update date:2022-08-03

Topics:

Authors:

Cha, Jin K.

Lewis, S. C.

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Article abstract of DOI:10.1016/S0040-4039(01)81579-3

The "chelation-controlled" Ireland-Claisen rearrangement of allylic glycolate esters is described in which the stereocontrol of the prochiral sp2 sites is achieved by the allylic oxygen substituent.

Full text of DOI:10.1016/S0040-4039(01)81579-3

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