Monohydride Complexes of Molybdenum(IV) and Tungsten(IV) containing Bulky Thiolate Ligands: X-Ray Crystal Structures of i3-2,4,6)3(PMe2Ph)2>, M = Mo or W

DOI: 10.1039/DT9910001813

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1813 - 1820 (1991)

Update date:2022-08-03

Topics:

Authors:

Burrow, Timothy E.

Hills, Adrian

Hughes, David L.

Lane, Janette D.

Morris, Robert H.

Richards, Raymond L.

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Article abstract of DOI:10.1039/DT9910001813

The complexes 1 (M = Mo or W, R = Me or Prⁱ) and their deuterio analogues have been prepared.The X-ray structures of 1 (M = Mo or W, R = Prⁱ) have been determined, showing the overall geometry in both to be based on a distorted trigonal-bipyramidal arrangement of thiolates with the phosphines essentially trans to each other.The hydride ligand could not be located by X-ray diffraction in either structure, but its presence is established by spectroscopic studies.The preparation of is also described.

Full text of DOI:10.1039/DT9910001813

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