Tetrahedron Letters p. 6169 - 6172 (1986)
Update date:2022-07-30
Topics:
Oare, David A.
Heathcock, Clayton H.
Preformed lithium enolates of ketones react with acyclic α,β-unsaturated ketones to give 1,5-diketones in good chemical yields.A strong correlation exists between enolate geometry and product stereochemistry; enolates having the Z configuration provide anti addition products while E enolates usually provide the syn diastereomers.
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