CYANO AND FLUORODESTANNYLATION: A NEW METHODOLOGY USING SOME POWERFUL SULFUR TRANSFER REAGENTS, THE ORGANOTIN SULFIDES

DOI: 10.1016/S0040-4039(00)96513-4

Source and publish data:

Tetrahedron Letters p. 4373 - 4376 (1987)

Update date:2022-08-03

Topics:

Authors:

Harpp, David N.

Gingras, Marc

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Article abstract of DOI:10.1016/S0040-4039(00)96513-4

Fluoride and cyanide ions destannylate bis(aralkyl)tin sulfides and trialkyltin sulfides giving, in the presence of a variety of alkyl and activated halides, the corresponding thioether derivatives in excellent yield.The conditions are mild, neutral and anhydrous; a strong solvent effect is noted.Special comments are made concerning work-up procedures.

Full text of DOI:10.1016/S0040-4039(00)96513-4

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