Journal of Organic Chemistry p. 2091 - 2095 (1985)
Update date:2022-08-05
Topics:
Bushey, Dean F.
Johnson, Brenda F.
Huang, Jamin
Four different classes of phosphate esters derived from enols, phenols, carbinols, and oximes have been shown to undergo intramolecular rearrangements assisted by a neighboring nitrogen.The unexpected products from these rearrangements have been characterized by spectral methods, especially 13C NMR.Rearrangements involving the O-ethyl S-propyl thiophosphate group have led to particularly interesting results.
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