Tetrahedron p. 8969 - 8984 (1991)
Update date:2022-08-05
Topics:
Barton, Derek H. R.
Blundell, Paul
Dorchak, Joseph
Jang, Doo Ok
Jaszberenyi, Joseph Cs.
Novel radical-chain deoxygenations of primary alcohols are described.The alcohols are acylated with the reagents pentafluorophenyl chlorothionoformate, 2,4,6-trichlorophenyl chlorothionoformate and 4-fluorophenyl chlorothionoformate and the intermediate thionocarbonates are deoxygenated with tributyltin hydride, triphenylsilane, diphenylsilane or phenylsilane in high-yielding reactions.Key Words: Thionocarbonates, Tributyltin hydride, Triphenylsilane, Diphenylsilane, Phenylsilane, Radical deoxygenations.
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