(Cyclopentadienone)ruthenium carbonyl complexes - A new class of homogeneous hydrogenation catalysts

DOI: 10.1021/om00127a027

Source and publish data:

Organometallics p. 1459 - 1461 (1985)

Update date:2022-07-31

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Authors:

Blum Blum

Czarkie Czarkie

Rahamim Rahamim

Shvo Shvo

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Article abstract of DOI:10.1021/om00127a027

[(η⁴-Ph₄C₄CO)(CO)₂Ru] ₂ and [(η⁴-Ph₂Me₂C₄CO)(CO) ₂Ru]₂ represent a new class of efficient precatalysts for homogeneous hydrogenation of alkenes, alkynes, ketones, aldehydes, and anthracene under moderate conditions. Mechanistic aspects have been investigated, and a basic catalytic cycle is proposed.

Full text of DOI:10.1021/om00127a027

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