Journal of the Chemical Society. Chemical communications p. 1707 - 1708 (1984)
Update date:2022-08-03
Topics:
Charrier, Claude
Mathey, Francois
Robert, Francis
Jeannin, Yves
Attack by lithium on 1,2-diphenyl-3,4-di-R-substituted-1,2-diphosphetes takes place on the endocyclic P-P bond when R=Ph whereas it takes place on the exocyclic P-Ph bond when R=tBu; in this latter case, a 1,2-diphosphet-1-yl anion is obtained which is probably stabilized by cyclic delocalization.
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