Bicyclic, Boatlike Cope Rearrangements. Probe for Conformational Preference by the Nodal Carbon Atoms

DOI: 10.1021/ja00306a023

Source and publish data:

Journal of the American Chemical Society p. 5739 - 5745 (1985)

Update date:2022-07-30

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Authors:

Doering, William von Eggers

Troise, Caroline Ann

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Article abstract of DOI:10.1021/ja00306a023

1,4-Bis(dideuteriomethylene)cyclohexane (1d0) and -cycloheptane (2d0) were rearranged thermally to 1,4-dimethylene-2,2,3,3-tetradeuteriocyclohexane (1d4) and -cycloheptane (2d4), respectively.The Arrhenius parameters for these intramolecular boatlike Cope

Full text of DOI:10.1021/ja00306a023

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