Bicyclic, Boatlike Cope Rearrangements. Probe for Conformational Preference by the Nodal Carbon Atoms

DOI: 10.1021/ja00306a023

Source and publish data:

Journal of the American Chemical Society p. 5739 - 5745 (1985)

Update date:2022-07-30

Topics:

Authors:

Doering, William von Eggers

Troise, Caroline Ann

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00306a023

1,4-Bis(dideuteriomethylene)cyclohexane (1d0) and -cycloheptane (2d0) were rearranged thermally to 1,4-dimethylene-2,2,3,3-tetradeuteriocyclohexane (1d4) and -cycloheptane (2d4), respectively.The Arrhenius parameters for these intramolecular boatlike Cope

Full text of DOI:10.1021/ja00306a023

Products guided by the article

Product name:1,4-bis<(dimethylamino)dideuteriomethylene>cyclohexane

Cas No:97135-82-5

R&D Labs maybe for 97135-82-5

Xinjiang Fufeng Biotechnologies Co., Ltd.

Contact:+86-539-7287111

Address:GANQUANPU INDUSTRIAL PARK, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT AREA (TOUTUNHE DISTRICT) OF URUMQI
Shanghai Dano Pharmaceutical Co.,Ld.(expird)

Contact:+86-592-6266840

Address:Building 1 Room 512, 720 Cailun Rd, Zhangjiang High-Tech Park, Shanghai 201203, China
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Anhui Hope-Chem Co., Ltd.

Contact:86-551-63540590

Address:No 1388 Furong Rd., Hefei, Anhui, China
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA

Relevant to this article

Visible-light-mediated arylation of: Ortho -hydroxyarylenaminones: Direct access to isoflavones

Doi:10.1039/c9cc09945j
(2020)
Synthesis of the Pyrrolidine Ring System by Radical Cyclization

Doi:10.1021/jo00350a038
(1985)
Preparation of 3-Methoxy-2-benzenesulfonylpropenenitriles

Doi:10.1055/s-1984-31073
(1984)
Synthesis of Stereoisomeric 4,9a-dimethylhydrodicyclopentacycloocten-1-ones Related to the Ophiobolins and Ceroplastins via Annelative Ring Expansion of Hydrindene Precursors

Doi:10.1021/jo00219a022
(1985)
Rhodium(I)-catalyzed homologation of aromatic aldehydes with trimethylsilyldiazomethane

Doi:10.1021/ja003608g
(2001)
Development of dual PLD1/2 and PLD2 selective inhibitors from a common 1,3,8-triazaspiro[4.5]decane core: Discovery of ML298 and ML299 that decrease invasive migration in U87-MG glioblastoma cells

Doi:10.1021/jm301782e
(2013)

Article Doi