Bicyclic, Boatlike Cope Rearrangements. Probe for Conformational Preference by the Nodal Carbon Atoms

DOI: 10.1021/ja00306a023

Source and publish data:

Journal of the American Chemical Society p. 5739 - 5745 (1985)

Update date:2022-07-30

Topics:

Authors:

Doering, William von Eggers

Troise, Caroline Ann

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00306a023

1,4-Bis(dideuteriomethylene)cyclohexane (1d0) and -cycloheptane (2d0) were rearranged thermally to 1,4-dimethylene-2,2,3,3-tetradeuteriocyclohexane (1d4) and -cycloheptane (2d4), respectively.The Arrhenius parameters for these intramolecular boatlike Cope

Full text of DOI:10.1021/ja00306a023

Products guided by the article

Product name:1,4-bis<(dimethylamino)dideuteriomethylene>cyclohexane

Cas No:97135-82-5

R&D Labs maybe for 97135-82-5

Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area
PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China

Relevant to this article

Visible-light-mediated arylation of: Ortho -hydroxyarylenaminones: Direct access to isoflavones

Doi:10.1039/c9cc09945j
(2020)
Synthesis of the Pyrrolidine Ring System by Radical Cyclization

Doi:10.1021/jo00350a038
(1985)
Preparation of 3-Methoxy-2-benzenesulfonylpropenenitriles

Doi:10.1055/s-1984-31073
(1984)
Synthesis of Stereoisomeric 4,9a-dimethylhydrodicyclopentacycloocten-1-ones Related to the Ophiobolins and Ceroplastins via Annelative Ring Expansion of Hydrindene Precursors

Doi:10.1021/jo00219a022
(1985)
Rhodium(I)-catalyzed homologation of aromatic aldehydes with trimethylsilyldiazomethane

Doi:10.1021/ja003608g
(2001)
Development of dual PLD1/2 and PLD2 selective inhibitors from a common 1,3,8-triazaspiro[4.5]decane core: Discovery of ML298 and ML299 that decrease invasive migration in U87-MG glioblastoma cells

Doi:10.1021/jm301782e
(2013)

Article Doi