Rearrangements of (2'-Propinyl)cyclohexadienols and -semibenzenes

DOI: 10.1002/hlca.19850680210

Source and publish data:

Helvetica Chimica Acta p. 355 - 370 (1985)

Update date:2022-08-03

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Authors:

Lukac, Josef

Heimgartner, Heinz

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Article abstract of DOI:10.1002/hlca.19850680210

The acid catalyzed dienol-benzene rearrangement of 3- and 5-methyl-substituted (2'-propinyl)cyclohexadienols has been investigated.Treatment of the dienols with CF3COOH in CCl4 yields allenyl- and (2'-propinyl)benzenes via <3,4>- and <1,2>-sigmatropic rea

Full text of DOI:10.1002/hlca.19850680210

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