Lewis Acid Mediated Thienium Cation Diels-Alder Reaction: A New Method for Regio- and Stereoselective Functionalization of 1,3-Dienes

DOI: 10.1016/S0040-4039(00)89135-2

Source and publish data:

Tetrahedron Letters p. 779 - 782 (1985)

Update date:2022-07-30

Topics:

Authors:

Fuji, Kaoru

Khanapure, Subhash P.

Node, Manabu

Kawabata, Takeo

Ito, Akichika

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Article abstract of DOI:10.1016/S0040-4039(00)89135-2

Under the influence of aluminium chloride the β-ethylthionitroolefin results in the formation of the thienium cation, which reacts with a variety of 1,3-dienes in the Diels-Alder sense.The cleavage of the resulting ring provides in one pot the 1,4-functio

Full text of DOI:10.1016/S0040-4039(00)89135-2

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