Generation and Trapping of Cyclopropene-3-carboxaldehyde and 2,3-Butadienal in Liquid Furan Photolysis

DOI: 10.1021/jo00217a002

Source and publish data:

Journal of Organic Chemistry p. 3034 - 3038 (1985)

Update date:2022-08-05

Topics:

Authors:

Rendall, W. Alan

Torres, Manuel

Strausz, Otto P.

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Article abstract of DOI:10.1021/jo00217a002

The photolysis of liquid furan at room temperature generated cyclopropene-3-carboxaldehyde and 2,3-butadienal, which were trapped as their Diels-Alder adducts with furan.In each case, both the exo and endo stereoisomers were obtained.The identity of these adducts, and also their stereochemistry, has been determined by MS, IR, and 1H and 13C NMR.

Full text of DOI:10.1021/jo00217a002

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