Effects of 16-Heterosubstitution on the Regiochemistry of the D-Homo Rearrangement

DOI: 10.1021/jo00219a031

Source and publish data:

Journal of Organic Chemistry p. 3604 - 3609 (1985)

Update date:2022-08-05

Topics:

Authors:

Bischofberger, Norbert

Walker, Keith A. M.

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Article abstract of DOI:10.1021/jo00219a031

The 16β-phenylthio-, 16β-phenylseleno-, and 16β-dimethylphenylsilyl-substituted 3β,17α-dihydroxy-5-pregnen-20-ones have been prepared by nucleophilic ring opening of 16α,17α-epoxysteroids in order to study the influence of the 16-substituent on the regioc

Full text of DOI:10.1021/jo00219a031

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