SYNTHESIS OF 2-DEOXY, 3-DEOXY, AND 2,3-DIDEOXY ANALOGS OF α,α-TREHALOSE BY REDUCTIVE DESULFONYLOXYLATION OF p-TOLUENESULFONATES WITH LITHIUM TRIETHYLBOROHYDRIDE

DOI: 10.1016/0008-6215(85)85207-1

Source and publish data:

Carbohydrate Research p. 335 - 346 (1985)

Update date:2022-08-04

Topics:

Authors:

Baer, Hans H.

Mekarska, Miroslawa

Boucher, Francine

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Article abstract of DOI:10.1016/0008-6215(85)85207-1

Lithium triethylborohydride reacts readily with the 2-tosylate, the 2,2'-ditosylate, the 2,3,2'-tritosylate, and the 2,3,2',3'-tetratosylate of 4,6:4',6-di-O-benzylidene-α,α-trehalose (1), to give products resulting both from O-desulfonylation and from re

Full text of DOI:10.1016/0008-6215(85)85207-1

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