PREPARATION OF A GLYCOSYL DONOR SUITABLE FOR SYNTHESIS OF GLYCOPROTEIN "CORE" OLIGOSACCHARIDES

Article abstract of DOI:10.1016/0008-6215(85)85203-4

2-O-Acetyl-3-O-allyl-4-O-benzyl-6-O-tert-butyldiphenylsilyl-D-glucopyranosyl chloride (14), a glycosyl donor suitable for synthesis of oligosaccharides corresponding to the N-glycoprotein saccharide "core", was synthesized by an efficient, six-stage route