INITIAL FORMATION OF AN OLEFIN-COPPER(I) ?-COMPLEX IN CONJUGATE ADDITION OF LITHIUM DIMETHYLCUPRATE TO t-BUTYL CINNAMATE

DOI: 10.1016/0022-328X(84)80079-0

Source and publish data:

Journal of Organometallic Chemistry p. C22 - C24 (1984)

Update date:2022-08-04

Topics:

Authors:

Hallnemo, Gerd

Olsson, Thomas

Ullenius, Christina

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(84)80079-0

The 13C NMR spectrum observed upon mixing lithium dimethylcuprate and t-butyl cinnamate in toluene-d8/THF at -70 deg C shows the signals of the olefinic carbons shifted to lower δ values.These are attributed as due to a ?-complex formed by coordination of copper to the carbon-carbon double bond of the cinnamate.

Full text of DOI:10.1016/0022-328X(84)80079-0

Products guided by the article

Product name:[(C₆H₅CHCHCO₂C(CH₃)3)Cu(CH₃)2]^(1-)*Li⁽¹⁺⁾=C₆H₅CHCHCO₂C(CH₃)3LiCu(CH₃)2

Cas No:97859-02-4

R&D Labs maybe for 97859-02-4

Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai
Jitat Company Ltd

Contact:852-27701081

Address:Room 2509, New Tech Plaza, 34 Tai Yau St., San Po Kong, HK
TAIXING BEST NEW MATERIALS CO., LTD

Contact:0523-87998158;

Address:No.18 Zhonggang Road，Taixing City ，Jiangsu , China
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China

Relevant to this article

Sulfur-Assisted Ring Expansion of the Potassium Salts of 1-Vinylcyclobutanols. A Versatile Synthesis of Cyclohexanones

Doi:10.1021/jo00223a033
(1985)
Doi:10.1021/ja00906a031
(1963)
Discovery and biological characterization of a novel series of androgen receptor modulators

Doi:10.1038/bjp.2008.107
(2008)
Studies on antidiabetic agents. 11. Novel thiazolidinedione derivatives as potent hypoglycemic and hypolipidemic agents

Doi:10.1021/jm00092a012
(1992)
Helical templating of oligopeptides by cyclodextrin dimers

Doi:10.1016/S0968-0896(03)00153-6
(2003)
Aldehyde dehydrogenase inhibitors: α,β-Acetylenic N-substituted aminothiolesters are reversible growth inhibitors of normal epithelial but irreversible apoptogens for cancer epithelial cells from human prostate in culture

Doi:10.1016/j.ejmech.2007.06.004
(2008)

Article Doi