Journal of Organic Chemistry p. 4596 - 4600 (1985)
Update date:2022-08-04
Topics:
Cohen, Theodore
Yu, Lin-Chen
Daniewski, Wlodzimierz M.
Readily available 2-(phenylthio)-1-vinylcyclobutanols undergo a facile potassium hydride induced ring expansion to 4-(phenylthio)cyclohexanones.The sulfur substituent plays a key role.Evidence for a fragmentation to an enone-anion intermediate is discusse
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