SYNTHESIS OF MYCAROSE AND EPI-AXENOSE FROM NON-CARBOHYDRATE PRECURSORS

DOI: 10.1016/0008-6215(85)85195-8

Source and publish data:

Carbohydrate Research p. 187 - 194 (1985)

Update date:2022-08-05

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Authors:

Roush, William R.

Hagadorn, Susannah M.

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Article abstract of DOI:10.1016/0008-6215(85)85195-8

A six-step synthesis of racemic mycarose from allylacetylene is described.Key transformations include the threo-selective epoxidation of (E)-4-methyl-1,4-heptadien-6-ol and the α-opening of xylo-4,5-epoxy-4-methylhept-1-en-6-ol (7), which was accomplished

Full text of DOI:10.1016/0008-6215(85)85195-8

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