Journal of Organometallic Chemistry p. C12-C14 (1985)
Update date:2022-08-03
Topics:
Fotheringham
Stephenson
Heterobimetallic complexes such as [η-areneMCl(SPPh2)2Pt(S2CNEt2)] (I, M = Ru, Os) and [η-C5Me5RhCl(SPPh2)2Pt(S2CNEt2)] (II) have been synthesised by reaction of NEt2H2[Pt(S2CNEt2)(Ph2PS)2] with either [M(η-arene)Cl2]2 or [Rh(η-C5Me5)Cl2]2 (2/1) molar ratio). Further reactions of I include facile chloride displacement with a range of neutral ligands L to give [η-areneML(SPPh2)2Pt(S2CNEt2)+ (III) cations and formation of tri- and penta-metallic species on treatment with more [Pt(S2CNEt2)(Ph2PS)2]-.
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