BENZYNE-INDUCED FRAGMENTATION OF 1,3-OXATHIOLANES. A NOVEL METHOD FOR DEPROTECTION OF CARBONYL GROUPS, PREPARATION OF PHENYL VINYL SULFIDES, AND 1,2-CARBONYL TRANSPOSITION

DOI: 10.1016/S0040-4039(00)98960-3

Source and publish data:

Tetrahedron Letters p. 2195 - 2198 (1985)

Update date:2022-07-29

Topics:

Authors:

Nakayama, Juzo

Sugiura, Hidetoshi

Shiotsuki, Atsuko

Hoshino, Masamatsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)98960-3

A variety of 1,3-oxathiolanes undergo a benzyne-induced fragmentation leading to phenyl vinyl sulfides and carbonyl compounds.The reaction developed here provides a novel method for deprotection of carbonyl compounds from 1,3-oxathiolanes, preparation of phenyl vinyl sulfides, and 1,2-carbonyl transposition.

Full text of DOI:10.1016/S0040-4039(00)98960-3

Products guided by the article

Product name:(5S,8R,9S,10S,13R,14S,17R)-17-((R)-1,5-Dimethyl-hexyl)-10,13-dimethyl-2-phenylsulfanyl-4,5,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene

Cas No:98204-63-8

R&D Labs maybe for 98204-63-8

SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Accendatech Co., LTD

Contact:+86-22-83718541

Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549

Relevant to this article

Pd-Catalysed Decarbonylation Free Approach to Carbonylative Esterification of 5-HMF to Its Aryl Esters Synthesis Using Aryl Halides and Oxalic Acid as C₁ Source

Doi:10.1002/chem.202101827
(2021)
Template-free synthesis of nanoporous gadolinium phosphonate as a magnetic resonance imaging (MRI) agent

Doi:10.1039/c5ra02004b
(2015)
Cationic Rhodium(I) Complexes of 1,4,8,11-Tetrathiacyclotetradecane (<14>aneS4) and the 6,6,13,13-Tetramethyl Analogue (Me4<14>aneS4). Preparation of Two Conformers, X-Ray Crystal Structure of (Rh<14>aneS4))2Cl2*MeCN, and Conformational Effect on the Nucleophilicity of the Rhodium(I) Ion

Doi:10.1039/c39850001137
(1985)
A dynamic micromixer for arbitrary control of disguised chemical selectivity

Doi:10.1039/b804530e
(2008)
Reaction of atomic carbon with isomeric cresols

Doi:10.2174/157017809790442907
(2009)
N-carbamate protected amino acid derived guanidine organocatalysts

Doi:10.1016/j.tet.2021.132093
(2021)

Article Doi