The reaction of trialkylstannylmethyllithium with α,β-epoxy ketones and α-chloro ketones

DOI: 10.1016/S0040-4020(01)86394-8

Source and publish data:

Tetrahedron p. 3281 - 3304 (1991)

Update date:2022-08-02

Topics:

Authors:

Sato, Tadashi

Kikuchi, Toshihiro

Tsujita, Hiroshi

Kaetsu, Atsushi

Sootome, Norio

Nishida, Ken-Ichiro

Tachibana, Kazutaka

Murayama, Eigoro

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Article abstract of DOI:10.1016/S0040-4020(01)86394-8

The reactions of trialkylstannylmethyllithium with α,β-epoxy ketones afforded mainly cyclopropanols, while α-chloro ketones afforded allyl alcohols and/or cyclopropanols, in varying amounts depending upon the molar ratio of the reagent to the substrate.

Full text of DOI:10.1016/S0040-4020(01)86394-8

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