Synthesis p. 427 - 431 (1994)
Update date:2022-08-04
Topics:
De Kimpe
Stanoeva
Boeykens
A convenient synthesis of monoacetals of α-diones, i.e. α-keto acetals, was developed by silver ion induced alcoholysis of regiospecifically formed α-bromo-α-chloro ketones. Similarly, the corresponding α,α-dialkoxy ketimines were synthesized from silver ion induced alcoholysis of α-bromo-α-chloro ketimines. Both methods provide an easy access to protected forms of α-diones, useful as building blocks in organic chemistry.
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Doi:10.1021/jo01355a010
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(2010)Doi:10.1021/jo00225a053
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(2019)